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A direct method for the synthesis of 1,2,5-triaryl-1H-imidazoles was achieved easily from cyclization of aryl acetaldehydes with amidines catalyzed by I2. Various substitued groups can be employed, and this reaction proceeds smoothly in moderate to good yields.

I2/TBPB mediated oxidative reaction of aryl acetaldehydes with amidines: synthesis of 1,2,5-triaryl-1H-imidazoles

I₂/TBPB mediated oxidative reaction of aryl acetaldehydes with amidines: synthesis of 1,2,5-triaryl-1H-imidazoles