English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

In this present investigation, we developed a new category of rhodanide anion based ternary gel polymer electrolytes (TILGPEs) with high electrochemical and thermal stability, which advantageously use the harmonizing properties of a temperature-responsive polymer poly vinylidene fluoride-co-hexafluoropropylene (PVdF-co-HFP) and room temperature ionic liquid (1-ethyl-3-methylimiazolium rhodanide (thiocyanate), (EMImSCN)). TILGPEs were fabricated using a facile solution cast method by incorporating EMImSCN and lithium rhodanide (LiSCN) into PVdF-co-HFP based membranes. Among the series of electrochemical tests including electrochemical impedance spectroscopy, cyclic voltammetry, linear sweep voltammetry and chronoamperometry, the membrane with 80 wt% electrolyte mixtures (EMImSCN/LiSCN) showed better performance in all aspects. The maximum ionic conductivity was found to be in the order of 2.8 × 10−4 S cm−1 at 298 K. The LiFePO4/TILGPE3/Li cell offered a maximum discharge capacity of 149.8 mA h g−1 at C/10 rate. The inimitable properties allowed the effective use of the rhodanide TILGPEs as active separators for the development of advanced lithium ion batteries.

rsc advances

Headway in rhodanide anion based ternary gel polymer electrolytes (TILGPEs) for applications in rechargeable lithium ion batteries: an efficient route to achieve high electrochemical and cycling performances