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Herein, in-situ reduction of bismuth and graphene oxide was performed by asolvothermal method under a nitrogen atmosphere, and the resulting Bi on RGOnanocomposites were used as an anode material for Mg-ion batteries. Thenanocomposite of 60% Bi:40% RGO is a beneficial anode material, delivering adischarge capacity as high as 413 and 372 mAh per g at the specific current of39 mA per g in the 1st and 50th cycles, respectively. In addition, it showshigh-rate capability with the discharge capacities of 381, 372, 354, 295, and238 mAh per g at the specific currents of 53, 100, 200, 500, and 700 mA per g,respectively. The better electrochemical performance of the nanocomposite isdue to improvement in the electronic conductivity and significant reduction ofvolume changes during electrochemical cycling. This study demonstrates thebismuth (Bi) on reduced graphene oxide (RGO) nanocomposite as a promisinghigh-capacity anode for magnesium-ion batteries with longer life cycle andhigh-rate performance.

In-situ Synthesis of Bismuth/Reduced Graphene Oxide Nanocomposites as High Capacity Anode Materials for Mg-ion Battery