English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

Three series of cyclometalated organoplatinum(II) complexes [Pt(p-MeC6H4)(bhq)(L)], in which bhq is benzo[h]quinolinate and L is PPh3 (1a), PPh2Me (1b), or PPhMe2 (1c); [Pt(p-XC6H4)(bhq)(PPh2Me)], in which X is H (2a), F (2b), tBu (2c), OMe (2d), or Me (2e = 1b); and [Pt(bhq)X(PPh2Me)], in which X is CF3CO2 (3a), Cl (3b), or I (3c) were synthesized and fully characterized using multinuclear (1H and 31P) NMR spectroscopy and elemental analysis. Typical complexes [Pt(p-MeC6H4)(bhq)(PPhMe2)], 1c, [Pt(p-MeC6H4)(bhq)(PPh2Me)], 2e, and [Pt(bhq)Cl(PPh2Me)], 3b, were further characterized by single crystal X-ray crystallography. The photophysical properties of all the complexes were studied and the influence of changing the ancillary ligands and substituents on their luminescence properties were investigated and the assignments were confirmed by TD–DFT calculations.

Influence of ancillary ligands on the photophysical properties of cyclometalated organoplatinum(ii) complexes