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Secondary amines are selectively obtained from low value startingmaterials using hydrogen and a non-noble metal-based catalyst.The reductive amination of aldehydes from nitroarenes or nitroalkanes is efficiently catalyzed by a well-defined diamino molybdenum sulfide cluster in a one-pot homogeneous reaction. Theintegrity of the molecular cluster catalyst is preserved along theprocess

Selective reductive amination of aldehydes from nitro compounds catalyzed by molybdenum sulfide clusters