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Decamethylmetallocenes form complexes (Cp* 2 Co + ){Sn IV Cl 2 (Pc˙ 3− )}˙ − ·2C 6 H 4 Cl 2  ( 1 ) and {(Cp*CrCl 2 )(Sn IV Cl(Pc 2− ))}·C 6 H 4 Cl 2  ( 2 ) whose structures and properties are discussed.

dalton transactions

Reaction of tin(<scp>iv</scp>) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc˙3−)}˙−·2C6H4Cl2

Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc˙3−)}˙−·2C6H4Cl2

Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = Cr^II and Co^II). Strong magnetic coupling of spins in (Cp*₂Co⁺){Sn^IVCl₂(Pc˙³⁻)}˙⁻·2C₆H₄Cl₂