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A μ-carbido diruthenium(iv) phthalocyanine complex was prepared for the first time from the free-base octabutoxyphthalocyanine by direct metalation with Ru 3 (CO) 12 . The first examples of the catalytic activity of Ru(iv) binuclear phthalocyanines were demonstrated by the cyclopropanation of aromatic olefins and carbene insertion into the N-H bonds of aromatic or aliphatic amines with turnover numbers of 680-1000 and 580-1000, respectively.

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Unexpected formation of a μ-carbido diruthenium(<scp>iv</scp>) complex during the metalation of phthalocyanine with Ru<sub>3</sub>(CO)<sub>12</sub> and its catalytic activity in carbene transfer reactions

Unexpected formation of a μ-carbido diruthenium(iv) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic activity in carbene transfer reactions

Unexpected formation of a μ-carbido diruthenium(iv) complex during the metalation of phthalocyanine with Ru₃(CO)₁₂ and its catalytic activity in carbene transfer reactions