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The borane adduct of the 2-(methylamido)pyridine anion, [mapyBH 3 ] - , has been incorporated into octahedral metal complexes. In fac-[Mn(κ 3 N,H,H-mapyBH 3 )(CO) 3 ] (1) and fac-[RuH(κ 3 N,H,H-mapyBH 3 )(CO)(PiPr 3 )] (2), which have been prepared by treating K[mapyBH 3 ] with fac-[MnBr(MeCN) 2 (CO) 3 ] and [RuHCl(CO)(PiPr 3 ) 2 ], respectively, it behaves as a tripod ligand, attached to the metal atom through the amido N atom and through two H atoms of the BH 3 moiety. X-ray diffraction analyses and theoretical studies (DFT, QTAIM) have shown that the MH 2 B atom grouping of 1 and 2 comprises two 3c-2e M-H-B interactions that are between those of the Shimoi type (κ 1 H coordination of the B-H bond) and those of the agostic type (κ 2 B,H coordination of the B-H bond). However, while both M-H-B interactions are almost identical in complex 1, this is not the case in complex 2, in which one M-H-B interaction is more agostic than the other due to the different trans influence of the hydride and phosphane ligands.

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Octahedral manganese(<scp>i</scp>) and ruthenium(<scp>ii</scp>) complexes containing 2-(methylamido)pyridine–borane as a tripod κ<sup>3</sup>N,H,H-ligand

Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine–borane as a tripod κ3N,H,H-ligand

Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine–borane as a tripod κ³N,H,H-ligand