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We report the synthesis, crystal structure, and dielectric, vibrational and emission spectra of two novel heterometallic perovskite-type metal-organic frameworks (MOFs) of the following formula: [(CH 3 ) 2 NH 2 ][K 0.5 Cr 0.5 (HCOO) 3 ] (DMAKCr) and [C 2 H 5 NH 3 ][K 0.5 Cr 0.5 (HCOO) 3 ] (EtAKCr). DMAKCr crystallizes in a trigonal structure (R3[combining macron] space group) and undergoes an order-disorder phase transition to the monoclinic system (P1[combining macron] space group) at about 190 K. The dielectric studies confirm the presence of first-order relaxor-like structural transformation. In the high-temperature phase, the dimethylammonium cations are dynamically disordered over three equal positions and upon cooling the dynamical disorder evolves into a two-fold one. This partial ordering is accompanied by a small distortion of the metal-formate framework. EtAKCr crystallizes in a monoclinic structure (P2 1 /n space group) with ordered EtA + cations and does not experience any phase transition. The differences in the thermal behavior caused by the substitution of Na + ions by larger K + ions in the [cat]M I M III (cat = DMA + , EtA + , M I = Na + , K + and M III = Cr 3+ and Fe 3+ ) heterometallic MOF family are discussed taking into account the impact of the hydrogen bond (HB) pattern and other factors affecting the stability of metal-formate frameworks. The optical studies show that DMANaCr and EtAKCr exhibit Cr 3+ -based emission characteristics for intermediate ligand field strength.

physical chemistry chemical physics/pccp. physical chemistry chemical physics

The effect of K+ cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K0.5Cr0.5(HCOO)3], where cat is protonated dimethylamine or ethylamine