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An unprecedented Fe 2 Pc 3 metallo-organic helicate has been assembled using a bidentate phthalocyanine (Pc) ligand, 2-formylpyridine and Fe(OTf) 2 . This giant helicate has proved itself as a host for large redox-active guests such as fullerene and naphthalenediimide derivatives. Photoactivated electronic interactions between components occur in the host-guest complex.

A giant M2L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

A giant M₂L₃ metallo-organic helicate based on phthalocyanines as a host for electroactive molecules