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The reaction of the chloroimidazolium chloride salt, [NHC-Cl][Cl], NHC = C{N(2,6- i Pr 2 C 6 H 3 )CH} 2  ( 1 ) with two equivalents of sodium phosphaethynolate, Na[OCP]·(dioxane) 2.5 , results in the formation of NHC-{cyclo-(CO)-P 2 -C(O)} ( 2 ) and NHC-P 2 -C(O)-NHC ( 3 ).

Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion

Synthesis of P₂C₂O₂ and P₂CO via NHC-mediated coupling of the phosphaethynolate anion