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A platinum catalyst supported on zirconia is proposed as a cathode in lithium-oxygen batteries. Experimental and theoretical studies show that zirconia suppresses the side-reactions of the intermediate (O 2  - ) and the final product (Li 2 O 2 ) by the stabilization of their reactivity. Thus, it is able to enhance the reversibility during charge/discharge in lithium-oxygen batteries.

A platinum catalyst deposited on a zirconia support for the design of lithium–oxygen batteries with enhanced cycling ability