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We report the effect of surfactant addition on the optical properties of perfluorinated polyanilines synthesized through liquid-liquid interfaces. We obtained very long Stokes shifts, 205 nm, for oligomers derived from a hydrofluoroether-water system in the presence of Triton X-100 as a surfactant, and vibronic fine features from a toluene-water system.

Long Stokes shifts and vibronic couplings in perfluorinated polyanilines