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A Ni(ClO 4 ) 2 -catalyzed enantioselective [2 + 2] cycloaddition of  N -allenamides with cyclic  N -sulfonylketimines was developed, which regioselectively occurred at the proximal CC bonds of the  N -allenamides.

chemical science

Enantioselective [2 + 2] cycloaddition of N-allenamides with cyclic N-sulfonylketimines: access to polysubstituted azetidines bearing quaternary stereocenters