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The papers mentioned in the title of the present comment article contain some calculations/results that are in disagreement with some basic concepts of chemistry.

rsc advances

Comments on “Experimental and theoretical studies of the nanostructured {Fe3O4@SiO2@(CH2)3Im}C(CN)3 catalyst for 2-amino-3-cyanopyridine preparation via an anomeric based oxidation”, RSC Adv., 2016, 6, 50100–50111, and “The first computational study for the oxidative aromatization of pyrazolines and 1,4-dihydropyridines using 1,2,4-triazolinediones: an anomeric-based oxidation”, RSC Adv., 2016, 6</b…