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A facile strategy has been developed to construct unique core–shell-structured Li 2.7 V 2.1 (PO 4 ) 3  nanocomposites with a Li 3 V 2 (PO 4 ) 3  core and LiVOPO 4  shell by using nonstoichiometric design and high-energy ball milling (HEBM) treatment.

rsc advances

Core–shell-structured Li3V2(PO4)3–LiVOPO4 nanocomposites cathode for high-rate and long-life lithium-ion batteries