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Select triarylsulfonium salts constitute ionic liquids with outstanding long-term, high-temperature aerobic stability (no mass loss in 90 days at 300 °C in air), making them among the most thermally stable organic materials known. A detailed analysis of their thermophysical properties reveals that lowering melting points in these salts by increasing ion size or lowering ion symmetry cannot be assumed, but remains an iterative process.

Thermally robust: triarylsulfonium ionic liquids stable in air for 90 days at 300 °C