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A new two dimensional (2D) Eu3+ coordination polymer, named [Eu(BTB)(H2O)2·solvent]n (1) (H3BTB = 4,4′,4′′-benzene-1,3,5-triyl-tribenzoic acid) has been constructed and investigated for sensing properties. Complex 1 shows structural flexibility originating from the 2D layer architecture, which could be triggered by the removal/restore of coordinated and guest solvent molecules. Benefiting from the high stability and intensive Eu3+ based emission of 1, it could be used as an effective fluorescence sensor for acetone with remarkable anti-interference and recyclability. In addition, the impact of structural features on the sensing performance of the complex was investigated, and enhanced sensing sensitivity was achieved with the desolvated complex.

Guest dependent structure and acetone sensing properties of a 2D Eu3+ coordination polymer

Guest dependent structure and acetone sensing properties of a 2D Eu³⁺ coordination polymer