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A novel homochiral porous MOF synthesized using ( R )-2,2′-dihydroxy-1,1′-binaphthyl-4,4′-dibenzoic acid was shown to be an effective heterogeneous catalyst for asymmetric Diels–Alder reaction between isoprene and  N -ethyl maleimide.

Enantioselective Diels–Alder reaction in the confined space of homochiral metal–organic frameworks