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New routes to functionalize the robust VA-polynorbornene skeleton by Pd-catalyzed cross-coupling reactions use  p -bromoaryl- and ω-bromoalkyl-VA-PNBs as versatile starting materials.

rsc advances

p-Bromoaryl- and ω-bromoalkyl-VA-PNBs: suitable starting materials for the functionalization of vinylic addition polynorbornenes via palladium-catalyzed cross-coupling reactions