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For the first time, magnetron sputtering of copper onto liquid was investigated for the preparation of stable blue-fluorescent copper nanoclusters. The fluorescent intensity increased linearly with an increase of mercaptan. Our finding casts light on the formation mechanism of metal photoluminescent nanoclusters via sputtering onto liquid.

Highly stable and blue-emitting copper nanocluster dispersion prepared by magnetron sputtering over liquid polymer matrix