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Photoinitiated thiol-yne reaction was combined with thermal thiol-epoxy to get thermosets by dual curing from propargyl decorated poly(ethyleneimine) and DGEBA.

rsc advances

Thiol-yne/thiol-epoxy hybrid crosslinked materials based on propargyl modified hyperbranched poly(ethyleneimine) and diglycidylether of bisphenol A resins