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Dynamically controlled construction of microstructures was demonstrated using a spirobenzopyran-containing poly(N-isopropylacrylamide). Under patterned light irradiation, the polymer accumulated at the irradiated area from a uniformly dissolved state and formed micro-patterned structures based on phase transition. Furthermore the microstructures were collapsed due to redissolution of the precipitated polymer when light irradiation was stopped.

Dynamically controlled construction of microstructures based on photo-induced phase transition of a spirobenzopyran-modified polymer solution