English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The realization of the nature of water coordination on the solid surfaces may provoke an essential understanding of T 1 relaxation enhancement, especially in nanoparticulate systems. We report herein that the T 1 relaxivity of Gd 2 O 3 nanoplates is highly dependent on water coordinating behaviors on different surfaces. Gd 2 O 3 nanoplates with metal-rich {100} facets showed an approximately 4-fold higher r 1 value compared to that with oxygen-terminated {111} facets. Density functional theory (DFT) calculations show that the enhanced T 1 relaxivity of Gd 2 O 3 {100} nanoplates may be ascribed to the high density of accessible Gd 3+ , fast exchange of water, and more importantly, multicenter (one-to-two) coordination for water molecules with magnetic centers on the metal-rich surface.

Water bridge coordination on the metal-rich facets of Gd2O3nanoplates confers high T1relaxivity

Water bridge coordination on the metal-rich facets of Gd₂O₃nanoplates confers high T₁relaxivity