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Use of an aminopolyalcohol-based Mn II complex in solvothermal Cu II chemistry leads to a rare example of a high nuclearity heterometallic {MnCu} system, in which four Cu II (H 1 Edte) units trap an inner {MnCu II } oxide core.

Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks

Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed Mn^II building blocks