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(C 10 H 7 )Te(CH 2 ) 4 Te(C 10 H 7 ) ( 1 ) and [(C 10 H 7 )Te(CH 2 ) 4 ]Br ( 2 ) are formed from Li[Te(C 10 H 7 )] and Br(CH 2 ) 4 Br. Treatment of 1 with CuBr affords [Cu 2 (μ-Br) 2 {μ-(C 10 H 7 ) 2 Te 2 (CH 2 ) 4 } 2 ] ( 3 ).

dalton transactions

Synthesis, characterization, and ligand behaviour of a new ditelluroether (C10H7)Te(CH2)4Te(C10H7) and the concurrently formed ionic [(C10H7)Te(CH2)4]Br