English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

An azadithiolate bridged monocyanide derivative [Fe 2 (adt)(CO) 5 (CN)] - of [Fe 2 (adt)(CO) 4 (CN) 2 ] 2- has been prepared and extensively characterized as a model of the [FeFe]-hydrogenase active site, using a combination of FTIR spectroscopy, electrochemical methods and catalytic assays with chemical reductants. The presence of two basic nitrogen sites opens up multiple protonation pathways, enabling catalytic proton reduction. To our knowledge [Fe 2 (adt)(CO) 5 (CN)] - represents the first example of a cyanide containing [FeFe]-hydrogenase active site mimic capable of catalytic H 2 formation in aqueous media.

Characterization of a monocyanide model of FeFe hydrogenases – highlighting the importance of the bridgehead nitrogen for catalysis