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Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).

A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

A pseudo-icosahedral cage {Gd₁₂} based on aminomethylphosphonate