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A high-nuclearity metal-cyanide cluster [Mo6Cu14] has been prepared and its photomagnetic properties investigated. The photoswitchable magnetic phenomenon observed is thermally reversible (T≈ 230 K). In the field of photomagnetism, [Mo6Cu14] represents a unique example of a nanocage and the highest nuclearity observed so far.

A high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties

A high-nuclearity metal-cyanide cluster [Mo₆Cu₁₄] with photomagnetic properties