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It is reported that well-dispersed coreandndash;shell Pd@Zn nanoparticles of controllable shell thickness can be synthesized from a Pd/CdSeandndash;ZnO precursor in H2andnbsp;without using a surfactant: the Pd ensembles on the material surface with electronic modulation by Zn atoms give a methanol turnover frequency (TOF) and selectivity of 3.3 andtimes; 10andminus;1andnbsp;sandminus;1andnbsp;and 80%, respectively, the yield of which is 2-fold the best reported value over other Pd-based catalysts.</p

Pd@Zn core–shell nanoparticles of controllable shell thickness for catalytic methanol production