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A novel macromolecular photoredox catalyst based on [Ru(bpy)3]2+ anchored to a 2nd-generation PAMAM dendrimer has been developed. Its catalytic activity under visible light irradiation and recyclability using organic solvent nanofiltration with a size-exclusion membrane have been explored under continuous flow conditions.

catalysis science and technology

Visible-light photoredox catalysis using a macromolecular ruthenium complex: reactivity and recovery by size-exclusion nanofiltration in continuous flow