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The results of dc and ac magnetization, heat-capacity, 57Fe Moessbauerspectroscopy, dielectric, pyroelectric current and isothermalmagneto-capacitance measurements on a recently reported lithium-based oxide,Li3FeRuO6, related to LiCoO2-type rhombohedral structure (space group, R-3m)are presented. The results reveal that the compound undergoes spin-glassfreezing below 15 K. There is a peak around 34 K in pyroelectric data, whichcan not be attributed to ferroelectricity, but to the phenomenon of thermallystimulated depolarization current. As revealed by magnetocapacitance data aboveand below magnetic ordering temperature, magnetic and electric dipoles appearto be coupled, thereby offering evidence for magnetodielectric coupling.

Spin-glass behavior and pyroelectric anomalies in a new lithium-based oxide, Li3FeRuO5