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We report the synthesis of a simple 1D Mn-azopyridine-based coordination polymer, poly-[MnII(NO3)2(OH2)2(azopy)2]·2MeCN (1) (azopy = 4,4′-azobis(pyridine)) and its use as a convenient feedstock to afford two 3D coordination polymers, namely: poly-[MnII(azopy)2(CNAgCN)4] (2), and poly-[MnII2(pda)(Hpda)2(azopy)2(OH2)2]·2MeCN (3), (pdaH2 = 1,4-phenylenediacetic acid). The compounds have been characterised by elemental analysis, IR, PXRD, TGA and single crystal X-ray diffraction. Compound 1 is a 1D coordination polymer while 2 represents a 3-dimensional coordination polymer adopting 2-fold interpenetrated rutile (rtl) topology and 3 is a 5-connected 3-dimensional coordination polymer with boron nitride (bnn) topology.

Facile adaptation of 1D Mn(ii) chain motifs to form 3D azo-pyridine-based coordination polymers