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Supramolecular Pd 2 L 4 cages (L = ligand) hold promise as drug delivery systems. With the idea of achieving targeted delivery of the metallacages to tumor cells, the bioconjugation of exo-functionalized self-assembled Pd 2 L 4 cages to peptides following two different approaches is reported for the first time. The obtained bioconjugates were analyzed and identified by high-resolution mass spectrometry.

Bioconjugation strategies to couple supramolecular exo-functionalized palladium cages to peptides for biomedical applications