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Stepwise construction of a 1D heterotrimetallic coordination polymer containing all three group 10 metal ions via an ammineplatinum(ii) metalloligand with d-penicillamine is reported. This system showed a significant enhancement in heterogeneous catalytic activity for electrochemical hydrogen evolution by the stepwise introduction of Pd II and Ni II into the Pt II metalloligand.

chemical communications

A platinum(<scp>ii</scp>)–palladium(<scp>ii</scp>)–nickel(<scp>ii</scp>) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution

A platinum(ii)–palladium(ii)–nickel(ii) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution