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Control of the structural type in metallic enantiopure and racemic radical cation salts is achieved through hydrogen bonding interactions between the chiral donor DM-EDT-TTF and the XF 6 anions (X = P, As, Sb), determined by the anion size and the chiral information.

chemical communications

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)<sub>2</sub>XF<sub>6</sub> (X = P, As, Sb)

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)₂XF₆ (X = P, As, Sb)