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A novel hexameric [MnNa 6 ] wheel-like aggregate consisting of [MnO] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnO] triangles, and the only one with a wheel-like metal topology.

A hexameric [MnIII18Na6] wheel based on [MnIII3O]7+ sub-units

A hexameric [MnIII18Na₆] wheel based on [MnIII3O]⁷⁺ sub-units