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Two novel green β-substituted Zn II -porphyrins, G1 and G2, based on a 4D-π-1A type substitution pattern have been synthesized. Their enhanced push-pull character, by reduction of H-L energy gaps, promotes broadening and red-shifting of absorption bands. The effective synthetic pathway and the remarkable spectroscopic properties make G2 ideal for BIPV application.

4D–π–1A type β-substituted ZnII-porphyrins: ideal green sensitizers for building-integrated photovoltaics

4D–π–1A type β-substituted Zn^II-porphyrins: ideal green sensitizers for building-integrated photovoltaics