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We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH 2 leads to an anionic substitution, which decreases the interaction among NH 2  - ions. The rotational properties of the high temperature polymorphs of KNH 2 are thereby retained down to room temperature.

KNH2–KH: a metal amide–hydride solid solution

KNH₂–KH: a metal amide–hydride solid solution