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An yttrium-tantalum oxynitride having a band gap of 2.1 eV (absorbing visible light at &lt;580 nm) was applicable as a semiconductor component of a Z-scheme CO2 reduction system operable under visible light, in combination with a binuclear Ru(ii) complex that has strong absorption in the visible region (&lt;600 nm). Excitation of this system with visible light under a CO2 atmosphere induced photocatalytic formation of formic acid with very high selectivity (&gt;99%).

chemical communications

A Z-scheme photocatalyst constructed with an yttrium–tantalum oxynitride and a binuclear Ru(<scp>ii</scp>) complex for visible-light CO<sub>2</sub> reduction

A Z-scheme photocatalyst constructed with an yttrium–tantalum oxynitride and a binuclear Ru(ii) complex for visible-light CO2 reduction

A Z-scheme photocatalyst constructed with an yttrium–tantalum oxynitride and a binuclear Ru(ii) complex for visible-light CO₂ reduction