English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

We report the preparation and characterization of two new polyoxothiometalate species, {Mo16} = {(Mo2O2S2)8(OH)16(C4O4)2}(4-) (compound 1) and {Mo12} = {(Mo2O2S2)6(OH)12(CH3COO)2}(2-) (compound 2). Control of synthesis is achieved by the addition of the organic-template and further re-arrangement is controlled simply by the addition of potassium to a precursor compound yielding compound 2. The structures of the compounds are discussed and we also show that ion-mobility mass spectrometry can be used to resolve the species and their building blocks in solution.

Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks