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The interaction of an anionic micelle with the molecular charges and dipole moments ensures the desired sequence of processes and suppresses cross reactions in an “all-green” photoredox catalytic access to hydrated electrons e˙−aq , which reductively decompose nonactivated chloro-organics.

chemical science

Combining energy and electron transfer in a supramolecular environment for the “green” generation and utilization of hydrated electrons through photoredox catalysis