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A gold( i )  N -heterocyclic carbene (NHC) ligand self-assembles with zinc( ii ) and cadmium( ii ) templates into bimetallic MII4L 6  cage frameworks.

AuICl-bound N-heterocyclic carbene ligands form MII4(LAuCl)6integrally gilded cages

Au^ICl-bound N-heterocyclic carbene ligands form MII4(LAuCl)₆integrally gilded cages