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A phenoxo bridged antiferromagnetic copper(II) cubane features a π-stacked 66-dia net framework and creates long range ferromagnetic ordering, as evidenced from a coercivity maximum (∼2000 Oe) at 20 K with very unusual saturation magnetization.

An unusual magnetic response in a π-stacked 66-dia net structure of [4 + 2] copper(ii) cubane

An unusual magnetic response in a π-stacked 6⁶-dia net structure of [4 + 2] copper(ii) cubane