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We report the structures and physical properties of two new iridates,NaIrO$_3$ and Sr$_3$CaIr$_2$O$_9$, both of which contain continuoustwo-dimensional honeycomb connectivity. NaIrO3 is produced by room temperatureoxidative deintercalation of sodium from Na$_2$IrO$_3$, and containsedge-sharing IrO6 octahedra that form a planar honeycomb lattice.Sr$_3$CaIr$_2$O$_9$, produced via conventional solid-state synthesis, hosts abuckled honeycomb lattice with novel corner-sharing connectivity between IrO6octahedra. Both of these new compounds are comprised of Ir$^{5+}$ (5$d^4$) andexhibit negligible magnetic susceptibility. They are thus platforms toinvestigate the origin of the nonmagnetic behavior exhibited by Ir$^{5+}$oxides, and provide the first examples of a $J$ = 0 state on a honeycomblattice.

New Honeycomb Iridium (V) Oxides: NaIrO$_3$ and Sr$_3$CaIr$_2$O$_9$