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Adsorption of azoles on thermodynamically inferior Cu 2 O(111) is so much stronger than on superior Cu 2 O(111)-w/o-Cu CUS  that it compensates its thermodynamic deficiency, unless the conditions are too oxygen rich and/or azole lean.

physical chemistry chemical physics/pccp. physical chemistry chemical physics

A DFT study of adsorption of imidazole, triazole, and tetrazole on oxidized copper surfaces: Cu2O(111) and Cu2O(111)-w/o-CuCUS