English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Two adamantane-bridged tripodal trisimidazolium or trisbenzimidazolium salts were designed as C3v-symmetrical tricarbene ligands and synthesized in good yields. The reaction of the tripodal trisazolium salt precursors with silver oxide provided trisilver hexacarbene complexes bearing a three-dimensional framework. Multinuclear NMR spectroscopy and mass spectrometry data showed that the complexes were symmetric structures of two tricarbene ligands, three metal ions, and three counter anions. X-ray crystallographic analyses revealed that both complex cations adopted a highly twisted conformation. The complex cations built from the trisimidazolium salts were arranged into columnar structures through CH/π interactions, which were assembled into a three-dimensional network structure by intermolecular CH/F interactions via hexafluorophosphate anions. The complex cations generated from the trisbenzimidazolium salts were aligned into columnar structures, which were arranged into a network structure through CH/π interactions. Solvents and counter anions were accommodated in the spaces of the crystalline lattices.

Synthesis and crystal structures of twisted three-dimensional assemblies of adamantane-bridged tris-NHC ligands and AgI

Synthesis and crystal structures of twisted three-dimensional assemblies of adamantane-bridged tris-NHC ligands and Ag^I