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We have synthesized Ni(II) and Al(III) 10-azacorroles through coordination-induced cyclisation of nitrogen-bridged bisdipyrrins. Al(III) 10-azacorrole displayed contrasting optoelectronic behaviours from Ni(II) 10-azacorrole, underlining the different electronic effects of the azacorrole ligand from the porphyrin.

The synthesis of NiII and AlIII 10-azacorroles through coordination-induced cyclisation involving 1,2-migration

The synthesis of Ni^II and Al^III 10-azacorroles through coordination-induced cyclisation involving 1,2-migration