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The formation of high aspect ratio supramolecular polymeric nanofibers from square-planar platinum(II) complexes through Pt···Pt and π-π stacking interactions has been achieved with a small width (&lt;15 nm), tunable length, and relatively narrow length distributions up to ca. 400 nm under conditions of kinetic control using small seed fibers as initiators.

Length control of supramolecular polymeric nanofibers based on stacked planar platinum(ii) complexes by seeded-growth