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Thiol-yne photopolymerization in miniemulsion is demonstrated as a simple, rapid, and one-pot synthetic approach to polythioether nanoparticles with tuneable particle size and clickable functionality. The strategy is also useful in the synthesis of composite polymer-inorganic nanoparticles.

Functional, composite polythioether nanoparticles via thiol–alkyne photopolymerization in miniemulsion